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Greek fire : ウィキペディア英語版
Greek fire

Greek fire was an incendiary weapon developed 672 and used by the Eastern Roman (Byzantine) Empire. The Byzantines typically used it in naval battles to great effect, as it could continue burning while floating on water. It provided a technological advantage and was responsible for many key Byzantine military victories, most notably the salvation of Constantinople from two Arab sieges, thus securing the Empire's survival.
The impression made by Greek fire on the west European Crusaders was such that the name was applied to any sort of incendiary weapon, including those used by Arabs, the Chinese, and the Mongols. These, however, were different mixtures and not the Byzantine formula, which was a closely guarded state secret. The composition of Greek fire remains a matter of speculation and debate, with proposals including combinations of pine resin, naphtha, quicklime, calcium phosphide, sulfur, or niter. Byzantine use of incendiary mixtures was distinguished by the use of pressurized nozzles or ''siphōn'' to project the liquid onto the enemy.
Although the term "Greek fire" has been general in English and most other languages since the Crusades, in the original Byzantine sources it is called by a variety of names, such as "sea fire" ( ''pŷr thalássion''), "Roman fire" ( ''pŷr rhōmaïkón''), "war fire" ( ''polemikòn pŷr''), "liquid fire" ( ''hygròn pŷr''), "sticky fire" ( ''pŷr kollētikón'') or "manufactured fire" ( ''pŷr skeuastón'').
==History==

Incendiary and flaming weapons were used in warfare for centuries prior to the invention of Greek fire. They included a number of sulphur-, petroleum-, and bitumen-based mixtures. Incendiary arrows and pots containing combustible substances were used as early as the 9th century by the Assyrians and were extensively used in the Greco-Roman world as well.
Furthermore, Thucydides mentions the use of tubed flamethrowers in the siege of Delium in 424 .〔Thuc. 4.100.1〕 In naval warfare, the fleet of the Byzantine Emperor Anastasius I (r. 491–518) is recorded by the chronicler John Malalas as having utilized a sulphur-based mixture to defeat the revolt of Vitalian in 515, following the advice of a philosopher from Athens called Proclus.
Greek fire proper, however, was developed in ''ca''. 672 and is ascribed by the chronicler Theophanes to Kallinikos (Latinized Callinicus), an architect from Heliopolis in the former province of Phoenice, by then overrun by the Muslim conquests. The accuracy and exact chronology of this account is open to question: Theophanes reports the use of fire-carrying and ''siphōn''-equipped ships by the Byzantines a couple of years before the supposed arrival of Kallinikos at Constantinople. If this is not due to chronological confusion of the events of the siege, it may suggest that Kallinikos merely introduced an improved version of an established weapon. The historian James Partington further thinks it likely that Greek fire was not in fact the creation of any single person but "invented by chemists in Constantinople who had inherited the discoveries of the Alexandrian chemical school". Indeed, the 11th-century chronicler George Kedrenos records that Kallinikos came from Heliopolis in Egypt, but most scholars reject this as an error. Kedrenos also records the story, considered rather implausible by modern scholars, that Kallinikos' descendants, a family called ''Lampros'', "brilliant", kept the secret of the fire's manufacture and continued doing so to Kedrenos' time.
Kallinikos' development of Greek fire came at a critical moment in the Byzantine Empire's history: weakened by its long wars with Sassanid Persia, the Byzantines had been unable to effectively resist the onslaught of the Muslim conquests. Within a generation, Syria, Palestine, and Egypt had fallen to the Arabs, who in set out to conquer the imperial capital of Constantinople. Greek fire was used to great effect against the Muslim fleets, helping to repel the Muslims at the first and second Arab sieges of the city. Records of its use in later naval battles against the Saracens are more sporadic, but it did secure a number of victories, especially in the phase of Byzantine expansion in the late 9th and early 10th centuries. Utilisation of the substance was prominent in Byzantine civil wars, chiefly the revolt of the thematic fleets in 727 and the large-scale rebellion led by Thomas the Slav in 821–823. In both cases, the rebel fleets were defeated by the Constantinopolitan Imperial Fleet through the use of Greek fire. The Byzantines also used the weapon to devastating effect against the various Rus' raids on the Bosporus, especially those of 941 and 1043, as well as during the Bulgarian war of 970–971, when the fire-carrying Byzantine ships blockaded the Danube.
The importance placed on Greek fire during the Empire's struggle against the Arabs would lead to its discovery being ascribed to divine intervention. The Emperor Constantine Porphyrogennetos (r. 945–959), in his book ''De Administrando Imperio'', admonishes his son and heir, Romanos II (r. 959–963), to never reveal the secrets of its composition, as it was "shown and revealed by an angel to the great and holy first Christian emperor Constantine" and that the angel bound him "not to prepare this fire but for Christians, and only in the imperial city". As a warning, he adds that one official, who was bribed into handing some of it over to the Empire's enemies, was struck down by a "flame from heaven" as he was about to enter a church. As the latter incident demonstrates, the Byzantines could not avoid capture of their precious secret weapon: the Arabs captured at least one fireship intact in 827, and the Bulgars captured several ''siphōns'' and much of the substance itself in 812/814. This, however, was apparently not enough to allow their enemies to copy it (see below). The Arabs, for instance, employed a variety of incendiary substances similar to the Byzantine weapon, but they were never able to copy the Byzantine method of deployment by ''siphōn'', and used catapults and grenades instead.
Greek fire continued to be mentioned during the 12th century, and Anna Komnene gives a vivid description of its use in a naval battle against the Pisans in 1099. However, although the use of hastily improvised fireships is mentioned during the 1203 siege of Constantinople by the Fourth Crusade, no report confirms the use of the actual Greek fire. This might be because of the general disarmament of the Empire in the 20 years leading up to the sacking, or because the Byzantines had lost access to the areas where the primary ingredients were to be found, or even perhaps because the secret had been lost over time.
Records of a 13th-century event in which "Greek fire" was used by the Saracens against the Crusaders can be read through the Memoirs of the Lord of Joinville during the Seventh Crusade. One description of the memoir says "... the tail of fire that trailed behind it was as big as a great spear; and it made such a noise as it came, that it sounded like the thunder of heaven. It looked like a dragon flying through the air. Such a bright light did it cast, that one could see all over the camp as though it were day, by reason of the great mass of fire, and the brilliance of the light that it shed."〔()〕
In the 19th century, it is reported that an Armenian by the name of Kavafian approached the government of the Ottoman Empire with a new type of Greek fire he claimed to have developed. Kavafian refused to reveal its composition when asked by the government, insisting that he be placed in command of its use during naval engagements. Not long after this, he was poisoned by imperial authorities, without their ever having found out his secret.〔 Adjarian, Hrachia. "Հայոց դերը Օսմանյան կայսրության մեջ," (role of Armenians in the Ottoman Empire ) ''Banber Erevani Hamalsarani'' 1967; trans. in Charles Issawi, ''The Economic History of Turkey, 1800-1914'', Chicago: University of Chicago Press, 1980, p. 64.〕

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